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Updated: Jul 4, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
09:58

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

二次アルキルトリフルオロボラートとアリル塩化物の効率的なクロスカップリング - - 微細スケールの並行実験を用いた反応発見

Spencer D Dreher1, Peter G Dormer, Deidre L Sandrock

  • 1Department of Process Research and the Catalytic Reactions Discovery and Development Laboratory, Merck and Co. Inc., 126 East Lincoln Avenue, Rahway, New Jersey 07065, USA. spencer_dreher@merck.com

Journal of the American Chemical Society
|June 28, 2008
PubMed
まとめ

研究者らは,オルガントリフルオロボラートと挑戦的なアリルハリドを結合するための新しい触媒システムを開発しました. この研究は,第2次アルキルボロンとアリル塩化物の結合を包括的に調査し,阻害された基板のためのメカニズムを明らかにした最初のものです.

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Overview
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