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Updated: Jul 4, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

"アンチ・バルドウィン"の3エクソディグサイクライゼーション:電子が少ないアルケーンからビニリデン・サイクロプロパン製剤を製造する

Matthew J Campbell1, Patrick D Pohlhaus, Geanna Min

  • 1Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3290, USA.

Journal of the American Chemical Society
|June 28, 2008
PubMed
まとめ

安定したカルバニオンは,SN2'置換によってプロパルギルハリドに循環し,ビニリデン・サイクロプロパネを生成する. この方法は,従来のカルベン反応では達成できないユニークなサイクロプロパン構造へのアクセスを提供します.

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