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Updated: Jul 4, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

炭素-窒素結合形成は,明確に定義されたアリル-銅 (III) 複合体を含む

Lauren M Huffman1, Shannon S Stahl

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA.

Journal of the American Chemical Society
|June 28, 2008
PubMed
まとめ

研究者らは,よく定義された銅 (III) -アリル種が,窒素核愛者と炭素-窒素結合を形成することを観察した. この発見は,ウルマン型結合反応の重要なステップに関する最初の直接的な証拠を提供します.

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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst09:12

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