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Updated: Jul 4, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
08:46

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)

Published on: November 22, 2016

末端リン酸化物M[トリプル結合]Pトリプル結合へのP2添加:サイクロ-P3複合体の合理的な合成

Nicholas A Piro1, Christopher C Cummins

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Room 6-435, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|July 1, 2008
PubMed
まとめ

この研究は,P2ユニットをディフォスファアジド複合体からフォスフィード基板に効率的に転送し,新しいサイクロ-P3複合体を形成することを実証しています. これらの発見は,分子P2.0のステキオメトリック転送が初めて成功したことを表しています.

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