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Updated: Jul 3, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

紫外線吸収スペクトロスコーピーと理論的なモデリングで研究されたAl(111) 表面上のアラネ群の形成と結合

Santanu Chaudhuri1, Sylvie Rangan, Jean-Francois Veyan

  • 1Applied Sciences Laboratory and Institute for Shock Physics, Washington State University, Spokane, Washington 99210-1495, USA.

Journal of the American Chemical Society
|July 19, 2008
PubMed
まとめ

アラネスは,水素貯蔵における重要な中間物質である. この研究は,アルミニウム表面にアルミニウム水化物 (AlH3) がどのように形成され,どのように移動するかを明らかにし,再水素化の動態を理解するために不可欠です.

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Infrared spectroscopy, also known as vibrational spectroscopy, is mainly used to determine the types of bonds and functional groups in molecules. In aldehydes and ketones, the carbonyl (C=O) bond shows an absorption around 1710 cm-1. The C=O bond vibration of an aldehyde occurs at lower frequencies than that of a ketone. In addition to the C=O absorption in an aldehyde, the aldehydic C–H bond also gives two peaks in the 2700–2800 cm-1 range. This absorption, coupled with the C=O stretching, is...
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