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Updated: Jul 3, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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安定したアニオンのN-ヘテロサイクルのカルベンとそのズウィテリオン複合体

Vincent César1, Noël Lugan, Guy Lavigne

  • 1Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France. Vincent.Cesar@lcc-toulouse.fr

Journal of the American Chemical Society
|August 6, 2008
PubMed
まとめ

研究者は,ピリミジニウムベータインを合成し,それを脱プロトン化して,マロナート基を持つ安定したN-ヘテロサイクリックカルベン (NHC) を形成した. これらのNHCリガンドは,Rh,Fe,Agで示されたズウィテリオン金属複合体の生成を可能にします.

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