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Updated: Jul 2, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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カーベンのウォルフ再配列における非統計的動力の証拠

Aviva E Litovitz1, Ivan Keresztes, Barry K Carpenter

  • 1Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.

Journal of the American Chemical Society
|August 15, 2008
PubMed
まとめ

合成された (13) C-ラベル付ディエルス・アルダー・アダクトを合成し,その溶解を研究した. 計算分析により,メチルピルヴォイルカルベンの驚くべき再配置経路が明らかになり,アセチルメチルケテンの形成とウォルフ再配置ダイナミクスに影響を与えました.

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