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Updated: Jul 2, 2026

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents
09:45

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents

Published on: November 12, 2016

有機分子のアルカリ金属還元:リチウムからの電子伝送が直接還元よりも速いのはなぜか

Neil V Rees1, Ronan Baron, Neil M Kershaw

  • 1Department of Chemistry, Physical and Theoretical Chemistry Laboratory, Oxford University, South Parks Road, Oxford, OX1 3QZ, UK.

Journal of the American Chemical Society
|August 22, 2008
PubMed
まとめ

この研究では,リチウム金属の還元における媒介体として4,4'-di-tert-butyl-1,1'-biphenyl (DBB) を使用することの運動的利点を定量化しています. DBBは,直接リチウム金属還元と比較して,有機合成における電子伝送運動を著しく加速します.

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