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Updated: Jul 2, 2026

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
09:17

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes

Published on: January 30, 2015

なぜ,フッ素アニオンは,ビニルシランとパラジウム (II) - ビニル複合体間の伝送を加速するのか? 理論的研究研究である

Akihiro Sugiyama1, Yu-ya Ohnishi, Mayu Nakaoka

  • 1Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.

Journal of the American Chemical Society
|September 5, 2008
PubMed
まとめ

フッ化物アニオンは,活性化エネルギーバリアを下げることで,パラジアム触媒によるクロスカップリング反応を著しく加速します. この加速は,強いシリコン-フッ化物結合と安定した移行状態の形成に起因する.

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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

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