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Updated: Jul 2, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

強化されたC-H活性化のために,フォスフィノエタンリガンドの触媒調節

Thomas R Cundari1, J Oscar C Jimenez-Halla, Glenn R Morello

  • 1Department of Chemistry and Center for Advanced Scientific Computing and Modeling, University of North Texas, P.O. Box 305070, Denton, Texas 76203-5070, USA. tomc@unt.edu

Journal of the American Chemical Society
|September 6, 2008
PubMed
まとめ

この研究では,dfmpeのような酸化フォスフィンリガンドを含むニッケル・ナイトレン複合体は,金属・アミンの形成を安定させることで,C−H結合の触媒性アミネーションを大幅に改善することを発見した. これは,以前の dtbpe リガンドの限界を克服します.

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