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Updated: Jun 30, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Pd触媒によるアミナ化反応の非常に活性な触媒である:アリルメシラートを用いたクロスカップリング反応と,アリル塩化物を用いたプライマリアミンの高度選択的モノアリレーション

Brett P Fors1, Donald A Watson, Mark R Biscoe

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|September 19, 2008
PubMed
まとめ

新しいビアリルモノフォスフィンのリガンドであるBrettPhosは,アリルメシラートを使用して効率的なC-Nクロスカップリング反応を可能にします. この触媒系は,低触媒負荷でアミンやアニリン,さらにはメチラミンさえも選択的単離化を実現します.

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