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Updated: Jun 29, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

チラルテトラアミノフォスフォニウムカルボキシラートで触媒化された直接マニッヒ型反応

Daisuke Uraguchi1, Yusuke Ueki, Takashi Ooi

  • 1Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan.

Journal of the American Chemical Society
|October 7, 2008
PubMed
まとめ

クイラル型テトラアミノフォスフォニウムカルボキシラート触媒は,高度にエナチオセレクティブなマニッヒ型反応を可能にします. オーガニックアニオンの構造的変化により,キラル四次元のオニウム塩の触媒能力が向上する.

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