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Updated: Jun 29, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
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Published on: August 23, 2018

コンペティティブC-I対C-CNは,Rh (III) 複合体からの還元性排除である. 選択性は溶媒によって制御される

Moran Feller1, Mark A Iron, Linda J W Shimon

  • 1Department of Organic Chemistry, Weizmann Institute of Science, Rehovot 76100, Israel.

Journal of the American Chemical Society
|October 14, 2008
PubMed
まとめ

RhIII複合体は,溶媒の極性によって2つの経路で選択的に反応する. プロティック溶媒はアセトニトリル除去を促進し,アプロティック溶媒はメチルヨウ酸化物の除去とイソニトリル形成を促進します.

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