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Updated: Jun 28, 2026

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
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Published on: January 16, 2016

水中のエステル水解のメカニズムの分子ダイナミクス予測

Hakan Gunaydin1, K N Houk

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.

Journal of the American Chemical Society
|October 23, 2008
PubMed
まとめ

生物学的ポリマーの水解は,ガスでは遅いが,水では速い. 分子ダイナミクスは,オートイオン化によって生成された水酸化物と水素素が,より迅速な反応のために,迅速かつ同時に酸塩触媒を可能にすることを明らかにします.

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