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Updated: Jun 28, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

オーガノプラチナム (II) エノラート複合物からβ-水素の除去のメカニズム的研究

Erik J Alexanian1, John F Hartwig

  • 1Department of Chemistry, University of Illinois, 600 South Mathews Avenue, Urbana, Illinois 61801, USA.

Journal of the American Chemical Society
|October 29, 2008
PubMed
まとめ

この研究では,プラチナ(II) エノラート複合体を調査し,β-水素の除去が熱分解の鍵であり,メタンとエノンを形成することを明らかにしました. 反応速度は,フォスフィン濃度とエノラート置換物の影響を受けます.

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