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Updated: Jun 28, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

C2対称ビスヒドラゾンは,不対称なスズキ-ミヤウラクロスカップリングにおけるリガンドとして作用する

Antonio Bermejo1, Abel Ros, Rosario Fernández

  • 1Departamento de Química Orgánica, Universidad de Sevilla, Apartado de Correos 1203, 41071 Seville, Spain.

Journal of the American Chemical Society
|November 5, 2008
PubMed
まとめ

新しいグリオキサルビスヒドラゾンリガンドにより,フォスフィンフリーで非対称なスズキ・ミヤウラ交叉結合が可能になる. この方法は,室温で高選択性でエナティオメリックに濃縮されたビアリルを効率的に生成します.

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