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Updated: Jun 28, 2026

Covalent Immobilization of Proteins for the Single Molecule Force Spectroscopy
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衝撃的な閉じ込め効果:ナノケージの空洞内のアミンに結合するAuCl4(-)

Juan D Henao1, Young-Woong Suh, Jeong-Kyu Lee

  • 1Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, E136, Evanston, Illinois 60208-3120, USA.

Journal of the American Chemical Society
|November 14, 2008
PubMed
まとめ

金(III) クロライド (AuCl4-) は,リガンド交換を通じてシロキサンナノケージ内のアミン群に結合し,プロトンが取れないままである. この結合は1:1の比率と,ナノケージ内のアミンプロトネーションのための重要なpHシフトを示しています.

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