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Updated: Jun 27, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

アリルおよびベンジルグリシジルエーターの金属媒介サイクリング:完全なシナリオ

Rocío Marcos1, Carles Rodríguez-Escrich, Clara I Herrerías

  • 1Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.

Journal of the American Chemical Society
|December 5, 2008
PubMed
まとめ

エナティオメリカルに純粋なアリルおよびベンジルグリシジルエーターは,鉄 (III) ブロミド/銀 (I) トリフラートを使用して,3-クロモナールまたはテトラヒドロベンゾ[c]オクセピン-4-オールに効率的にサイクルされます. 金の触媒は効果が低いので,Friedel-Crafts反応のメカニズムを示している.

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