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Updated: Jun 27, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

アルキニルcyclopropanolsのステレオセレクティブ,二重モードルテニウム触媒リング拡張のアルキニルcyclopropanolsの

Barry M Trost1, Jia Xie, Nuno Maulide

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA. bmtrost@stanford.edu

Journal of the American Chemical Society
|December 5, 2008
PubMed
まとめ

ルテニウム触媒は,アルキニルcyclopropanolsの新しいリングの拡張を可能に, (Z) -アルキリデンのcyclobutanonesまたはベータ置換のcyclopentenonesのいずれかを高い選択性で得ます. これは,ルテニウム触媒反応におけるユニークな反応パターンを強調しています.

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