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Updated: Jun 27, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
09:12

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

マクロサイクルの二酸化銅 ((I) 複合体によるO2活性化によるシグマ*内分子芳香水酸化の完全なメカニズム

Albert Poater1, Xavi Ribas, Antoni Llobet

  • 1Modeling Laboratory for Nanostructures and Catalysis (MoLNaC), Dipartimento di Chimica, Universita degli Studi di Salerno, via Ponte don Melillo, Fisciano (SA), 84084, Italy.

Journal of the American Chemical Society
|December 6, 2008
PubMed
まとめ

この研究は,二銅 (I) 複合体を使用した分子内芳香性水酸化のメカニズムを詳細に説明しています. 酸素活性化におけるスーパーオクソとペロクソ種のような重要な中間物質を明らかにし,将来の触媒設計を導く.

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