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Updated: Jun 27, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

プラチナ (II) とパラジウム (II) メチル複合体のプロトノリシスにおける水素トンネル掘削:メカニズム的な意味合い

John E Bercaw1, George S Chen, Jay A Labinger

  • 1Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|December 6, 2008
PubMed
まとめ

量子トンネリングは,プラチナとパラジウムによって触媒化されたアルカンの酸化で観察される. この発見は,これらの触媒系におけるトンネル掘削と金属-炭素結合の直接プロトノリシスの関連性を示唆しています.

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Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride

Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
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Reduction of Alkenes: Catalytic Hydrogenation

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

Introduction
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

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Regioselectivity of Electrophilic Additions-Peroxide Effect

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Radical Anti-Markovnikov Addition to Alkenes: Mechanism

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