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Updated: Jun 26, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
12:19

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

フォトクロミックなダイアリレタンを含むイオン性液体とN-ヘテロサイクリックカルベン

Vivian Wing-Wah Yam1, Jason Ka-Wai Lee, Chi-Chiu Ko

  • 1Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, PR China. wwyam@hku.hk

Journal of the American Chemical Society
|January 6, 2009
PubMed
まとめ

研究者らは,金,銀,パラジウム用の新しい光色ダイアリレチンベースのN-ヘテロサイクリックカルベン (NHC) を開発した. これらの化合物は,可逆の光色反応と調節可能な発光性を表し,光スイッチ可能な金属含有物質と触媒を可能にします.

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Photochemical Electrocyclic Reactions: Stereochemistry

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.
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