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Updated: Jun 26, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
09:12

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

cis-およびtrans- ((ピリジン) 2Pd ((OAc) H: Pd ((0) による分子酸素の活性化メカニズムと,直接挿入による活性化メカニズムを比較する

Jason M Keith1, William A Goddard

  • 1Materials Process and Simulation Center, MC (139-74), California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|January 13, 2009
PubMed
まとめ

量子力学は,分子酸素がパラジウム-ヒドリド複合体とどのように反応するかを明らかにします. Pd(0) 経路は,シスおよびトランス同位体の両方の直接挿入よりも,特に酸の補助で好ましい.

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Expression and Purification of Nuclease-Free Oxygen Scavenger Protocatechuate 3,4-Dioxygenase

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Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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Cycloaddition Reactions: MO Requirements for Photochemical Activation

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