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Updated: Jun 25, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

イリジウム触媒によるC-H活性化とスズキ・ミヤウラ反応を用いて,高効率な機能群をアロマティックなメインチェーンポリマーに組み込む

Tae Soo Jo1, Se Hye Kim, Jihoon Shin

  • 1Department of Chemistry, University of Nevada Las Vegas, 4505 Maryland Parkway, Box 454003, Las Vegas, Nevada 89154-4003, USA.

Journal of the American Chemical Society
|February 5, 2009
PubMed
まとめ

この研究では,bis (((pinacolato) diboron.を用い,アーロマティックポリスルフォンのイリジウム触媒化ボリレーションを導入しています. この方法により,ボリル化ポリスルフォンが効率的に生成され,スズキ-ミヤウラクロスカップリングによる多用途な機能化が可能になります.

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