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Updated: Jun 25, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

ルテニウム触媒によるアミンとスルフォナミドのN-アルキレーションは,水素を借りる方法論を用いて行われています

M Haniti S A Hamid1, C Liana Allen, Gareth W Lamb

  • 1Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, United Kingdom.

Journal of the American Chemical Society
|February 5, 2009
PubMed
まとめ

ルテニウム触媒は,アルコールを用いて効率的なアミンアルキル化を可能にし,プライマリアミンを二次アミン,二次アミンを三次アミンに変換します. この方法はまた,N-ヘテロサイクリングとスルフォナミドアルキル化を促進し,汎用的な合成経路を提供します.

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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction10:39

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Preparation of Amines: Alkylation of Ammonia and Amines

Alkylation is one of the methods used to prepare amines. Direct alkylation of ammonia or a primary amine with an alkyl halide gives polyalkylated amines along with a quaternary ammonium salt through successive SN2 reactions. This process of making the quaternary salt through the direct alkylation method is called exhaustive alkylation.
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Preparation of 1° Amines: Azide Synthesis

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