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Updated: Jun 25, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

アリルシアン化物の直接触媒的非対称添加は,ケトンに添加される

Ryo Yazaki1, Naoya Kumagai, Masakatsu Shibasaki

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|February 14, 2009
PubMed
まとめ

この研究は,アリルシアン化物をケトンに非対称的に加えるための新しい触媒的方法を導入しています. このプロセスは,Z構成の不飽和ニトリルで光学的に濃縮された三次アルコールを生成し,幅広い基板範囲を示しています.

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