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ボールミルでの多成分凝縮反応による分子ナノ構造の合成

Burçak Içli1, Nicolas Christinat, Justus Tönnemann

  • 1Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|February 19, 2009
PubMed
まとめ

ボールメーリングにより,最大3.1 nmの大きな分子ケージが作られます. この機械化学的アプローチは,建築ブロックを効率的に凝縮して複雑な超分子構造にします.

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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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