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Updated: Jun 25, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

カーボラニル単位を組み込んだジルコナサイクロペンテンの合成,構造,および反応性

Shikuo Ren1, Hoi-Shan Chan, Zuowei Xie

  • 1Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, People's Republic of China.

Journal of the American Chemical Society
|February 28, 2009
PubMed
まとめ

新しいジルコナサイクロペンテンのカルボラン複合体が合成され,従来の合成経路で入手できない多様なカルボラン誘導体を作るためのユニークなエントリーポイントを提供しました.

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Aromatic Hydrocarbon Cations: Structural Overview

Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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