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Updated: Jun 25, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

移行状態の歪みエネルギーは,1,4-二酸化水素化および芳香分子ダイエルス-アルダーサイクル添加の活性化エネルギーと相関する

Amy E Hayden1, K N Houk

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive, Los Angeles, California 90095-1569, USA.

Journal of the American Chemical Society
|March 5, 2009
PubMed
まとめ

計算化学は,移行状態の歪曲エネルギーが,反応エネルギーがそうでない場合でも,多循環芳香炭化水素二酸化水素化およびダイエルス・アルダー反応における反応性を予測することを明らかにします. この発見は,化学反応経路の理解を助けます.

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