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Updated: Jun 25, 2026

Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis
14:11

Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis

Published on: March 29, 2016

移行金属ベースの水素原子移転反応における基底状態エントロピーの傾向

Elizabeth A Mader1, Virginia W Manner, Todd F Markle

  • 1Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA.

Journal of the American Chemical Society
|March 12, 2009
PubMed
まとめ

移行金属複合体は,オキシルラジカルによる水素原子移転 (HAT) 反応の間に,著しい負のエントロピー変化を示します. これは有機分子と対照的であり,HAT熱力学における金属中心の重要性を強調しています.

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