リチウムカルバマートにおけるNからCのアリル移行:ベンジルアルコールのアルファアリレーション

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Updated: Jun 25, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

Jonathan Clayden1, William Farnaby, Damian M Grainger

  • 1School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK. clayden@man.ac.uk

Journal of the American Chemical Society
|March 12, 2009
PubMed
まとめ

研究者らは,リチア化O-ベンジルカルバメトで新しいN-to-Cアリレーションを発見した. この反応により,α,α-arylated アルコールが生成され,これまでに知られている方法よりもエネルギー要求が低い新しい合成経路が提供されます.

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