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Updated: Jun 24, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
07:50

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

ニトロアルケンの直接非対称マイケルの添加:二核亜鉛触媒によるヴィニログスの核好性

Barry M Trost1, Julien Hitce

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.

Journal of the American Chemical Society
|March 14, 2009
PubMed
まとめ

二核触媒は,2~5H) -フランオンの直接結合添加をニトロアルケーンに可能にします. この反応は高いステレオ選択性で進行し,多用途なマイケル・アダクトを良好な収穫で生み出します.

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