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Updated: Jun 24, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

インドロカルバゾール含有 [2] ロタキサンによる相互接続した宿主アニオン認識

Asha Brown1, Kathleen M Mullen, Jay Ryu

  • 1Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, OX1 3TA UK.

Journal of the American Chemical Society
|March 20, 2009
PubMed
まとめ

この研究では,最初のインドロカルバゾール含有 [2] ロタキサン,新しい分子機械を導入しています. この相互接続した構造は,協力的な水素結合を通じて,塩化物およびブロミドアニオンの認識が強化されていることを示しています.

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Selection Rules: Thermal Activation
Conjugated systems containing an even number of π-electron pairs undergo a conrotatory ring closure. For example, thermal electrocyclization of (2E,4E)-2,4-hexadiene, a conjugated diene containing two π-electron pairs, gives trans-3,4-dimethylcyclobutene.
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