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Updated: Jun 24, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

サイクロペンタディエニルアレンリガンドの汎用的な調整と,チタン触媒によるエチレントリメリゼーションにおけるその役割

Edwin Otten1, Aurora A Batinas, Auke Meetsma

  • 1Center for Catalytic Olefin Polymerization, Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.

Journal of the American Chemical Society
|March 26, 2009
PubMed
まとめ

アンサリガンドを含むカチオンチタンの複合体は,エチレントリメリゼーションを触媒化する. メタル-アレンの相互作用は,光譜法とDFTを用いて研究され,触媒に関連する調整モードを明らかにした.

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