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Updated: Jun 24, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

アルカリゲン・キシロソキシダン・サイトクロームc'におけるヘム-NO結合の活性化パラメータは,解離的メカニズムによる推定ディニトロシル中間形態である

David A Pixton1, Christine A Petersen, Alicja Franke

  • 1Department of Chemistry and Biochemistry, Eastern Oregon University, One University Boulevard, La Grande, Oregon 97850-2899, USA.

Journal of the American Chemical Society
|April 2, 2009
PubMed
まとめ

アルカリゲンシロキシダンシトクロームc' (AXCP) は5座標の独特のヘム-ニトロシル複合体を形成し,溶解性ガニア酸サイクラゼとNO結合の類似性を共有しています. アクティベーションパラメータは,遠端および近端ヘム面でのNO結合のメカニズムを明らかにします.

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