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Updated: Jun 24, 2026

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
09:54

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

Published on: September 12, 2018

アリルイオジドのpd触媒化C-Nクロスカップリング反応のための効率的なプロセス:制御要因の洞察

Brett P Fors1, Nicole R Davis, Stephen L Buchwald

  • 1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139.

Journal of the American Chemical Society
|April 8, 2009
PubMed
まとめ

この研究は,パラジアム触媒によるC-Nクロスカップリング反応におけるヨウ素酸ナトリウム (NaI) の抑制効果を克服しています. 特定の溶媒とビアリルフォスフィンのリガンドを使用することにより,アリルヨウ酸化物と様々なアミンの効率的な結合が達成されました.

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