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Updated: Jun 23, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

メタル・オーガニック・フレームワークに機能群を導入するための保護と脱保護アプローチ

Teppei Yamada1, Hiroshi Kitagawa

  • 1Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan. teppei@chem.kyushu-univ.jp

Journal of the American Chemical Society
|April 21, 2009
PubMed
まとめ

研究者は,メタル・オーガニック・フレームワーク (MOF) に機能群を導入するための新しい保護,複合,および脱保護 (PCD) 方法を開発しました. この新しい技術は,大きな孔を持つMOFを成功裏に合成し,材料科学のための多用途性を実証しました.

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関連する概念動画

Protecting Groups for Aldehydes and Ketones: Introduction01:23

Protecting Groups for Aldehydes and Ketones: Introduction

Protecting groups are compounds that can bind to a specific functional group in the presence of other functional groups to protect them from undesired chemical reactions. These compounds can selectively bind to particular functional groups and advance chemoselective reactions in polyfunctional systems (Figure 1). After the functional group has served its purpose, it is removed by reacting it with specific compounds.
Protection of Alcohols02:31

Protection of Alcohols

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Protection
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Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

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Introduction to Functional Groups02:08

Introduction to Functional Groups


Functional groups are group of atoms with specific chemical properties that occur within organic molecules and sometimes denoted as “R”. Functional groups are found along the carbon backbone of macromolecules can form chains or rings of carbon atoms. Functional groups can “functionalize” a compound by enabling it to adopt different physical and chemical properties.
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The table below summarizes some of the major functional groups in organic chemistry. (The...
Overview of Advanced Functional Groups02:22

Overview of Advanced Functional Groups


Functional groups are groups of atoms with specific chemical properties that occur within organic molecules and are sometimes denoted as “R”. Functional groups can “functionalize” a compound by enabling it to adopt different physical and chemical properties.
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Acetals and Thioacetals as Protecting Groups for Aldehydes and Ketones01:24

Acetals and Thioacetals as Protecting Groups for Aldehydes and Ketones

Acetals are formed by reacting two equivalents of alcohol with carbonyl compounds like aldehydes or ketones. Acetals are unaffected by bases, nucleophiles, oxidizing agents, and reducing agents. They serve as protecting groups for aldehydes and ketones. Acetals can be easily formed and also easily removed via mild acid hydrolysis.
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