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Updated: Jun 23, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

ニッケルによって触媒化された1,2-ダイエンのシアノエステル化

Yasuhiro Hirata1, Tomohiko Inui, Yoshiaki Nakao

  • 1Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.

Journal of the American Chemical Society
|April 22, 2009
PubMed
まとめ

ニッケル触媒は,1,2-ジエンのシアノエステル化をシアノフォーマートエステルで促進し,β-シアノアルファ-メチレンアルカノアートを産生する. これらの製品は,アイソメリゼーションまたはさらなる反応を経て,代用されたアクリロニトリル誘導体を形成することができます.

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