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Updated: Jun 23, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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ビピリジンとディアザブタジエンのデカメチルテルボセンの複合体:多構成基底状態とオープンシェルのシングレット形成

Corwin H Booth1, Marc D Walter, Daniel Kazhdan

  • 1Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA. chbooth@lbl.gov

Journal of the American Chemical Society
|April 24, 2009
PubMed
まとめ

デカメチルイテルボセンの複合体は,f-軌道占有により,中間のバレンスを示し,開いた殻のシングレット形成を示す. この発見は,オルガノランタニド化合物とf元素化学における異常な磁性を明らかにする.

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