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Updated: Jun 23, 2026

Solid-phase Synthesis of [4.4] Spirocyclic Oximes
05:15

Solid-phase Synthesis of [4.4] Spirocyclic Oximes

Published on: February 6, 2019

SmI(2) と H(2) O2) を用いたサイクル1,3-ダイエスターの選択的還元

Giuditta Guazzelli1, Sara De Grazia, Karl D Collins

  • 1School of Chemistry, University of Manchester, UK.

Journal of the American Chemical Society
|May 9, 2009
PubMed
まとめ

サマリウム (II) ヨド化物 (SmI2) を水で混ぜると,過度な還元なしに,周期的1,3-ダイースターを選択的に3ヒドロキシ酸に還元します. この選択性は,電子移転とラジカル-アニオン安定化から生じる.

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