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Updated: Jun 23, 2026

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
04:38

Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions

Published on: July 28, 2022

ストレントアルキンとアルケンの1,3-二極サイクロアディションにおけるアジドの反応性と地域選択性:計算による研究

Franziska Schoenebeck1, Daniel H Ess, Gavin O Jones

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.

Journal of the American Chemical Society
|May 23, 2009
PubMed
まとめ

この研究では,計算的方法を使用して1,3-二極サイクロアディションを調査しています. サイクロアルケニンはサイクロアルケニンよりも反応性があり,反応性はリングサイズと置換物によって影響を受けます.

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Electrophilic Addition to Alkynes: Halogenation

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If a set of reactants can yield multiple constitutional isomers, but one of the isomers is obtained as the major product, the reaction is said to be regioselective. In such reactions, bond formation or breaking is favored at one reaction site over others.
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