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Updated: Jun 22, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
08:46

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)

Published on: November 22, 2016

安定したフォスフォニウムシロイリドで,シロ-ウィッティッグの反応剤として反応性がある

David Gau1, Tsuyoshi Kato, Nathalie Saffon-Merceron

  • 1Universite de Toulouse, UPS, LHFA, and CNRS, LHFA UMR 5069, F-31062 Toulouse, France.

Journal of the American Chemical Society
|June 6, 2009
PubMed
まとめ

研究者は,安定したフォスフォニウムシライリド,フォスフォニウムイリドのシリコンアナログを合成しました. この新しい化合物は,シラ-ウィティッグ反応剤として作用し,カルボニルと新しい化学反応を可能にします.

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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

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Aldehydes and Ketones to Alkenes: Wittig Reaction Overview

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Aldehydes and Ketones to Alkenes: Wittig Reaction Mechanism

The Wittig reaction, which converts aldehydes or ketones to alkenes using phosphorus ylides, proceeds through a nucleophilic addition‒elimination process.
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Preparation and Reactions of Sulfides

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Carboxylic Acids to Acid Chlorides

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α-Bromination of Carboxylic Acids: Hell–Volhard–Zelinski Reaction

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SN2 Reaction: Transition State

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When the nucleophile approaches the electrophilic carbon with its lone pairs, the halide acts as a leaving group and moves away with the electron-pair bonded to the carbon. Dotted partial bonds represent the bonds being formed or broken...