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Updated: Jun 22, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
10:39

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction

Published on: August 23, 2018

ルテニウムラセミゼーション触媒のリガンド交換におけるCOアシスタンス:アシル中間物質の特定

Jenny B Aberg1, Jonas Nyhlén, Belén Martín-Matute

  • 1Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.

Journal of the American Chemical Society
|June 19, 2009
PubMed
まとめ

研究者らは,タート-ブトオキシドを用いて,エタ(5) - (((Ph(5) Cp) Ru(CO) ((2) Clの活性化中に重要なアシル中間物質を特定した. この発見は,炭素一酸化物 (CO) の援助によってリガンド交換が起こり,COリガンドに対する核愛性の攻撃を含むことを確認しています.

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