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Updated: Jun 22, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
12:08

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes

Published on: June 24, 2022

Rh ((I)) 触媒によるエナチオセレクティブ水素化における電子効果の起源の可能性

Hai-Chen Wu1, Shafida Abd Hamid, Jin-Quan Yu

  • 1Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW.

Journal of the American Chemical Society
|June 27, 2009
PubMed
まとめ

リガンドの電子密度の減少は,ロジウム (((I)) -触媒化された水金属化における地域選択性を変化させる. この電子チューニングはまた,キラル誘導を逆転させ,非対称な水素化メカニズムに関する新しい洞察を提供します.

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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex10:52

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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