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Updated: Jun 22, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
08:46

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)

Published on: November 22, 2016

強く極化されたP-P結合を持つディホスフィンは,コヴァレンント分子と,柔軟な分子構造を持つドナー-受容体アダクトのハイブリッドである

Sebastian Burck1, Kathrin Götz, Martin Kaupp

  • 1Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70550 Stuttgart, Germany.

Journal of the American Chemical Society
|July 3, 2009
PubMed
まとめ

研究者らは,P-フォスフォリル置換のN-ヘテロサイクリックフォスフィンを調査し,非常に柔軟なP-P結合を明らかにしました. これらの債券は,変数的な長さとユニークな特性を有しており,従来の共性債券分類に異議を唱えています.

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Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers07:14

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

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