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Updated: Jun 21, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

カチオンロジウム ((I) -dppf 複合体触媒オレフィンイソメリゼーション/プロパルギル クレイゼン再配列/カルボニル移行カスケード

Ken Tanaka1, Eri Okazaki, Yu Shibata

  • 1Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan. tanaka-k@cc.tuat.ac.jp

Journal of the American Chemical Society
|July 18, 2009
PubMed
まとめ

ロジウム ((I) -dppf触媒は,アルリルプロパルギルエーテルを適度な温度でアルレン酸アルデヒドに効率的に変換します. さらに加熱すると,カルボニル移動が促進され,十分な量のダイナールが生成されます.

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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