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Updated: Jun 21, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

レーニウム触媒によるフェノールの地域選択性アルキル化

Yoichiro Kuninobu1, Takashi Matsuki, Kazuhiko Takai

  • 1Division of Chemistry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University, Tsushima, Kita-ku, Okayama 700-8530, Japan. kuninobu@cc.okayama-u.ac.jp

Journal of the American Chemical Society
|July 23, 2009
PubMed
まとめ

レーニウム触媒反応は,フェノールとアルケーンから,モノアルキル化フェノール誘導体を効率的に生成します. この地域選択合成は,オルト・ポジションやパラポジションを標的とし,有機化学にとって貴重な方法を提供している.

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The addition of hydrogen bromide to alkenes in the presence of hydroperoxides or peroxides proceeds via an anti-Markovnikov pathway and yields alkyl bromides.
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If a set of reactants can yield multiple constitutional isomers, but one of the isomers is obtained as the major product, the reaction is said to be regioselective. In such reactions, bond formation or breaking is favored at one reaction site over others.
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