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Updated: Jun 21, 2026

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
07:30

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones

Published on: January 21, 2020

酸化オルガノカタリシスによるエナチオセレクティブアルデヒドアルファ-ニトロアルキレーション

Jonathan E Wilson1, Anthony D Casarez, David W C MacMillan

  • 1Merck Center for Catalysis, Princeton University, Princeton, New Jersey 08544, USA.

Journal of the American Chemical Society
|July 25, 2009
PubMed
まとめ

研究者らは,アルデヒドの最初のエナンチオセレクティブ有機触媒性アルファ-ニトロアルキル化を開発した. この新しい方法は,β-ニトロアルデヒドと貴重なβ-アミノ酸を効率的に合成します.

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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes09:54

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