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Updated: Jun 21, 2026

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents
09:45

A Protocol for Safe Lithiation Reactions Using Organolithium Reagents

Published on: November 12, 2016

サイクロペンタノン,サイクロヘクサノン,アセトフェノン,ベンジルケトンのリチウムエノラートの溶液構造. トリプルイオンとより高いリチアート複合体

Kristopher J Kolonko1, Margaret M Biddle, Ilia A Guzei

  • 1Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.

Journal of the American Chemical Society
|July 29, 2009
PubMed
まとめ

リチウムエノラートは,様々な溶媒でテトラムおよびジマーを含む多様な構造を示します. HMPAやアミンのような添加物は,これらの構造に影響を与え,モノマー,トリプルイオン,四重イオンを形成し,同位体特有の行動が観察される.

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α-Alkylation of Ketones via Enolate Ions

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Ionic Crystal Structures

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