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Updated: Jun 21, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Pd触媒によるスズキ・ミヤウラクロスカップリング反応におけるヘクサケーション性デンドリフォスリガンド:範囲とメカニズム研究

Dennis J M Snelders1, Gerard van Koten, Robertus J M Klein Gebbink

  • 1Chemical Biology and Organic Chemistry, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands.

Journal of the American Chemical Society
|July 31, 2009
PubMed
まとめ

パラジウムとデンドリフォス結合体を使用した新しい触媒系は,スズキ-ミヤウラ交互結合反応において高い活性を示しています. このシステムは,低パラジウム負荷でアリル塩化物とブロミドを効率的に結合し,従来の触媒の性能を上回ります.

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